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The batteries of tomorrow: Project CaSino

Innovative material development for sustainable calcium-sulphur batteries



In the CASINO collaborative project, researchers at KIT, together with other partners, are exploring the potential of calcium-sulfur batteries as an alternative to lithium-ion batteries.
In the CASINO collaborative project, researchers at KIT, together with other partners, are exploring the potential of calcium-sulfur batteries as an alternative to lithium-ion batteries.

Minerals are essential for the function of human body cells: They control blood clotting, regulate the water balance, support our immune system and help build bones and teeth. Calcium plays a particularly important role in the latter. A mineral for stability. A potential that can also be exploited in battery research?

A team at the Helmholtz Institute Ulm (HIU) led by Dr. Zhirong Zhao-Karger, Group Leader for Advanced Battery Materials at the Institute of Nanotechnology (INT), is researching this. The PhD chemist has set herself the task of researching calcium-sulphur batteries as an alternative to lithium-ion batteries for commercial applications. “The steady expansion of electromobility and renewable energy storage will lead to a shortage of raw materials. Projections already predict that there will not be enough lithium for the increasing electrification. We need an available, long-term and sustainable alternative to relieve the pressure on the lithium market and meet battery demand at the same time,” explains Zhao-Karger.

In the CaSino joint project coordinated by the German Aerospace Center (DLR), Zhao-Karger, together with four other research institutes and two industrial companies, is investigating the potential of calcium-sulphur batteries with the involvement of an industrial advisory board. The combination offers several advantages over lithium-ion: Calcium is one of the five most common elements worldwide and is therefore around 400 times more common than lithium. In addition, the high storage capacity and cell voltage are ideal for a battery application. Sulphur as a counterpart also offers a high storage capacity and would also be recycled as a by-product of the refinery. A win-win situation.

Dr. Zhirong Zhao-Karger, Dr. Sibylle Riedel, and Dr. Christian Arnobäücker (from left to right) are working, among other things, on improving a non-corrosive boron-based electrolyte.
Dr. Zhirong Zhao-Karger, Dr. Sibylle Riedel, and Dr. Christian Arnobäücker (from left to right) are working, among other things, on improving a non-corrosive boron-based electrolyte.

However, both substances also have a less pleasant property: their reactivity. When discharging, sulphur forms a soluble intermediate product in the electrolyte that accumulates on the anode. Calcium also forms surface layers on contact with the electrolyte. These passivations can lead to a reduced service life of the battery. These are challenges that the research consortium is tackling in the project with experimental investigations, analyses and modeling. The HIU has developed a stable and non-corrosive boron-based electrolyte to counteract the reactivity of the calcium. The sulphur is to be bound by a polymer. “In the first step, we developed a new electrolyte as the basis for the cell structure. With the subsequently constructed cell, we can now carry out electrochemical tests to show that the calcium-sulphur compound works on the one hand and to optimize the cycle stability and service life of the battery on the other,” says Zhao-Karger, describing the procedure. The aim of the project is to build an industrial demonstrator cell, which will then be tested by an industrial project partner.

 

Images:

  • Amadeus Bramsiepe / KIT

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